Advances from synthesis to applications yaochen zhenga,b, sipei li a, zhulin weng, and chao gaoa received in xxx, xxx xth xxxxxxxxx 20xx, accepted xth xxxxxxxxx 20xx doi. Their globular and dendritic architectures endow them with unique structures and properties such as abundant functional groups, intramolecular cavities, low viscosity, and high solubility. The microstructure, viscoelastic behavior, mechanical property thermal stability, and ionic conductivities of the ionogels are investigated. This thesis describes the development of a novel route for preparation of hyperbranched polymers. Geared to novices and experts alike, hyperbranched polymers is a musthave resource for anyone working in polymer architectures, polymer engineering, and functional materials. Catechol groups have been incorporated into macromolecules as main, side and endchain groups by employing various synthetic pathways. Request pdf synthesis of hyperbranched polymers by photoinduced metal free atrp a novel synthetic strategy for the syntheses of hyperbranched homo and block copolymers was developed. Hyperbranched polymers and its modified polymers have varying solubility, compatibility, thermal stability, reactivity, electrochemical, luminescence properties, etc. Due to their unique physical and chemical properties and potential applications in various fields from drugdelivery to coatings, interest in hyperbranched polymers is growing rapidly, as confirmed by the increasing number of publications. Hyperbranched polymers all problems solved after 15 years of research. Hyperbranched polymers hbps have shown widespread academic and commercial success in the preparation of films and novel materials, and now are emerging into the biomedical research space as nanocarriers for use in drug delivery and diagnostics. Hyperbranched polymers are less perfect molecules but still possess the highly branched architecture with a multitude of endgroups.
Albena lederer,walther burchard published on 20150820 by royal society of chemistry. A linear polymer, hyperbranched polymers with various degrees of branching, and 100% hyperbranched polymers were successfully synthesized by selfpolycondensation of 2,2,2trifluoro144phenoxyphenoxyphenylethanone by using different amounts of trifluoromethanesulfonic acid from the same ab2 monomer. In order to take advantage of this potential, the underlying phase behaviour must be known. From the thermodynamic point of view, the modelling of these phase diagrams is quite challenging, because the thermodynamic properties depend on the. Without additionally introducing a fluorescent probe, novel nanoengineered peptidegrafted hyperbranched polymers npghps are constructed for their combined outstanding antimicrobial activity and sensitive bacterial. Such polymers are usually prepared in an easy and affordable onepot synthesis and therefore are considered suitable for industrial largescale applications such as coating and resins formulation. Hyperbranched polymers show an outstanding potential for applications ranging from chemistry over nanotechnology to pharmacy. The results not only provide an effective method to tune the structure and molecular weights of hyperbranched polymers in confined. Interfacial and demulsifying behavior of novel fluorinated. Synthesis of hyperbranched polymers by free radical additioncoupling polymerization with a 3 b 2 and a 2 a. Pdf hyperbranched polymers of unique compositions were studied for their mechanical properties and degradation behaviors. Hyperbranched polymers is the first book to examine in detail the recent advances in hyperbranched polymers.
Hyperbranched polymers wiley online books wiley online library. A new family of chemical crosslinked ionogel is successfully synthesized by photopolymerization of hyperbranched aliphatic polyester with acrylate terminal groups in an ionic liquid of 1butyl3methylimidazolium tetrafluoroborate bmimbf4. Hyperbranched polymers with controlled degree of branching. Synthesis and characterisation of hyperbranched polymers. While linear polymers are almost entirely used for fabricating polymer materials, hyperbranched. Tetraphenylcyclopentadienebased hyperbranched polymers.
History of hyperbranched polymers as shown in table 1, showing the development of hyperbranched polymers, highly branched arti. The free radical polymerization of divinyl monomers was reported. Dendrimers and hyperbranched polymers material selection. Download it once and read it on your kindle device, pc, phones or tablets. Pdf chapter 2 hyperbranched polymers ahmad reza taheri.
Siliconcontaining hyperbranched polymers sihbps have drawn much attention due to their promising applications. Assembly of hyperbranched polymers and its biomedical. Helps the reader gain a better understanding of irregular branching and its relationship to a polymers properties and potential applications, aiding in the design of highly functional materials. While linear polymers are almost entirely used for fabricating polymer materials, hyperbranched polymers hbps have attracted significant. The development of hyperbranched polymers is a rapidly expanding field in the area of macromolecular science.
Journal of applied polymer science 2015, 2 20, nana. In many cases, the hyperbranched polymers are discussed as a more rapidly prepared and more economical replacement for perfect dendrimers in special applications. The reaction of equimolar amounts of dvb and n buli results in the formation of. Hyperbranched polymers by albena lederer overdrive. Synthesis of hyperbranched polymers by photoinduced metal. There is great commercial interest in hyperbranched polymers from manufacturers of polymer formulations, additives and coatings, polymer electronics and pharmaceuticals. It discusses in detail the synthesis strategies for these particular classes of polymers as well as biocompatible and biodegradable hbps, which are of increasing interest to polymer technologists due to their immense potential in biomedical. Control of polymer topology through transitionmetal. Thermoresponsive and reducible hyperbranched polymers. By controlling the competition between propagation and chain transfer with 1, the free radical polymerization of ethylene glycol dimethacrylate 3 afforded soluble hyperbranched polymers. Hyperbranched polymers are highly branched macromolecules with threedimensional dentritic architecture.
This book presents a comprehensive study on a new class of branched polymers, known as hyperbranched polymers hbps. Structure of hyperbranched polyglycerol and amphiphilic polyglycerol esters in dilute aqueous and nonaqueous solution. Due to their unique topological structure and interesting physicalchemical properties, hbps have attracted wide attention from both academia and industry. Hyperbranched polymers, an important subset of dendritic macromolecules, are highly branched, and have 3d globular nanopolymeric architectures. Selfassembly of phospholipidanalogous hyperbranched polymers nanomicelles for drug delivery. Thermoresponsive and reducible hyperbranched polymers synthesized by raft polymerisation by anna tochwin 1, alaa elbetany 1, hongyun tai 1.
Hyperbranched polymers hbps are highly branched macromolecules with a three. Focusing on the structural characterization of hyperbranched polymers, the book summarizes the research in the field and makes a direct correlation between the chemical structure and global molecular properties. Today it is known that this is true for many aspects, for example, both types. Preparation of hyperbranched polymers by controlledliving.
Hps can be facilely synthesized via a onepot polymerization of traditional small molecular monomers. Nanoengineered peptidegrafted hyperbranched polymers for. Facing the global health crisis caused by drugresistant bacteria, antimicrobial peptides and their analogues offer exciting solutions to this widespread problem. Hyperbranched polymers with multiple alkyl bromide peripheral groups were synthesized by the copolymerization of styrene with ethylene glycol dimethacrylate 2. Pdf hyperbranched polymers engineering materials and. Recent progress on hyperbranched polymers synthesized via. Synthesis of structurally controlled hyperbranched. Influence of branching architecture on polymer properties pages. Pei polymers of various molecular weights were the first potential dispersants tested. Fengxia sun, xiaoling luo, lichao kang, xiayu peng, chunxia lu. Hyperbranched polymers from divinylbenzene and 1,3. However, the construction of sihbps, especially those containing functional aromatic units in the branched backbones by the simple and efficient piersrubinsztajn pr reaction, has been rarely developed.
Recent progress on hyperbranched polymers synthesized. Hyperbranched polymers are polymers based on axbmonomers, ie, monomers having one bfunctionality and two or more agroups resulting in polymers with a potential branching point in each repeat unit. Hyperbranched polymer an overview sciencedirect topics. Figure 2 showed the dewatering time for the three fluorinated hyperbranched polymers in oil solutions at concentrations of 20200 ppm, where the ordinate represents the time required for separating the water layer to 37 ml, and the abscissa represents the concentrations of the polymer added to the oil.
Hyperbranched polymers were synthesized using anionic selfcondensing vinyl polymerization ascvp by forming inimer initiator within a monomer in situ from divinylbenzene dvb and 1,3diisopropenylbenzene dipb using anionic initiators in thf at 40 degreesc. New method to access hyperbranched polymers with uniform. Synthesis, properties, and applications wiley series on polymer engineering and technology book 7 kindle edition by yan, deyue, gao, chao, frey, holger. Phase diagrams for systems containing hyperbranched polymers. Hyperbranched polymers hps are highly branched threedimensional 3d macromolecules. Thus, hyperbranched polymers and its modified polymers have a wide range of applications in many fields such as ranging from engineering to nano and medical fields. Future trends in the synthesis and application of hyperbranched polymers. The aim is to produce hyperbranched polymers via enhanced deactivation atrp without crosslinking even at high conversion. Our strategy will be to use excess cui1 to control gelation, so called enhanced deactivation atrp.
Use features like bookmarks, note taking and highlighting while reading hyperbranched polymers. Comparison of hyperbranched macromolecules with linear polymers and dendrimers. Hyperbranched polymers hps are highly branched threedimensional 3d. One of the properties of dendrimers is they can be made water soluble unlike most synthetic polymers. Synthesis and applications of hyperbranched polymers. Synthesis of structurally controlled hyperbranched polymers using a. Polymer materials are indispensable to our modern society and enrich the quality of our lives. Hyperbranched polymers by deyue yan overdrive rakuten. How hyperbranched polymers compare with dendrimers as well as linear polymers. Hyperbranched polymers differ from dendrimers by their lack of the. Pdf hyperbranched polymers for coating applications. Hyperbranched polymers are a subclass of dendritic molecules characterised by a highly branched architecture.
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